I agree with everything Sherry said. Training through punishment is doomed to fail, and will often have unexpected consequences (like just general resentment towards you, or added stress which can manifest itself in many different ways). The fact that he is pooping in a chair is not any sort of retaliation, it's probably something like:
* he finds the litterbox situation to be unacceptable in some way. Maybe it's the litter, or the smell, or the location of the box, or that it isn't clean enough, or that there aren't enough litterboxes (some cats won't poop and pee in the same box).
or
* there is some type of physical ailment that is causing him discomfort when he "goes", and since he is not getting any help solving that ailment, he is searching for "creative" ways to maybe find a place he can go where it won't hurt or be uncomfortable.
Even if you could use negative reinforcement to train him not to go on the chair, it would be foolhardy to do so, because then he'd just have to pick a different place, and there's no guarantee that his new choice would be any better. Not only that but unless the punishment came at exactly the same time he was elimination on the chair, then for all he knows you could be punishing him for something completely different, and that's where the unexpected consequences comes in.
_________________ The little monsters 3
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